N,N-Dimethylaniline CAS NO.121-69-7
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- Product Details
Keywords
- dye
- Organic intermediate
- intermediate
Quick Details
- ProName: N,N-Dimethylaniline
- CasNo: 121-69-7
- Molecular Formula: C8H11N
- Application: Dye intermediate
- DeliveryTime: 30 DAYS after payment
- PackAge: In barrels or bags
- Port: SHANGHAI
- ProductionCapacity: 50 Metric Ton/Day
- Purity: 99min
- LimitNum: 1 Metric Ton
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Details
Substances
Formula : C8H11N
Molecular weight : 121,18 g/mol
CAS-No. : 121-69-7
EC-No. : 204-493-5
Index-No. : 612-016-00-0
Component Classification Concentration
N,N-Dimethylaniline
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Acute Tox. 3; Carc. 2; Aquatic Chronic 2; H301, H331, H311, H351, H411 |
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<= 100 % |
For the full text of the H-Statements mentioned in this Section, see Section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
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If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a
physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section
2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media Do NOT use water jet.
5.2 Special hazards arising from the substance or mixture
Carbon oxides, Nitrogen oxides (NOx)
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
Use water spray to cool unopened containers.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate
ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of
vapours accumulating to form explosive concentrations. Vapours can accumulate in low
areas.
For personal protection see section 8.
6.2 Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
6.3 Methods and materials for containment and cleaning up
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
earth, diatomaceous earth, vermiculite) and place in container for disposal according to
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local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
electrostatic charge.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Components with workplace control parameters
8.2 Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately
after handling the product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and
approved under appropriate government standards such as NIOSH (US) or EN
166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove
removal technique (without touching glove's outer surface) to avoid skin contact
with this product. Dispose of contaminated gloves after use in accordance with
applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU)
2016/425 and the standard EN 374 derived from it.
Full contact
Material: butyl-rubber
Minimum layer thickness: 0,3 mm Break through time: 480 min
Material tested:Butoject® (KCL 897 / MIT-IVY Z677647, Size M)
Splash contact Material: Nitrile rubber
Minimum layer thickness: 0,4 mm
Break through time: 30 min
Material tested:Camatril® (KCL 730 / MIT-IVY Z677442, Size M)
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The life science business of Merck operates as MilliporeSigma in
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data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail
sales@kcl.de, test method: EN374
If used in solution, or mixed with other substances, and under conditions which
differ from EN 374, contact the supplier of the CE approved gloves. This
recommendation is advisory only and must be evaluated by an industrial hygienist
and safety officer familiar with the specific situation of anticipated use by our
customers. It should not be construed as offering an approval for any specific use
scenario.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must
be selected according to the concentration and amount of the dangerous substance
at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-
face respirator with multi-purpose combination (US) or type ABEK (EN 14387)
respirator cartridges as a backup to engineering controls. If the respirator is the sole
means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Discharge into the environment must be avoided.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
a) Appearance Form: liquid
Colour: light yellow
b) Odour No data available
c) Odour Threshold No data available
d) pH 7,4 at 1,2 g/l at 20 °C
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e) Melting point/freezing point |
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Melting point/range: 1,5 - 2,5 °C - lit. |
|
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f) Initial boiling point and boiling range |
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193 - 194 °C - lit. |
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g) Flash point 75 °C - closed cup
h) Evaporation rate No data available
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i) Flammability (solid, gas) |
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No data available |
|
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j) Upper/lower flammability or explosive limits |
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Upper explosion limit: 7 %(V) Lower explosion limit: 1 %(V) |
k) Vapour pressure 13 hPa at 70 °C
1 hPa at 30 °C
l) Vapour density 4,18 - (Air = 1.0)
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m) Relative density 0,956 g/cm3 at 25 °C
n) Water solubility ca.1 g/l
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o) Partition coefficient: n-octanol/water |
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log Pow: 2,62 |
|
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p) Auto-ignition temperature |
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No data available |
|
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q) Decomposition temperature |
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No data available |
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
Surface tension 3,83 mN/m at 2,5 °C
|
Relative vapour density |
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4,18 - (Air = 1.0) |
SECTION 10: Stability and reactivity
10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
Heat, flames and sparks.
10.5 Incompatible materials
Strong oxidizing agents, Strong acids, Acid chlorides, Acid anhydrides, Chloroformates,
Halogens
10.6 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen
oxides (NOx)
Other decomposition products - No data available
In the event of fire: see section 5
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
LD50 Oral - Rat - 951 mg/kg
Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Tremor.
Cyanosis
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LD50 Dermal - Rabbit - 1.692 mg/kg
Skin corrosion/irritation Skin - Rabbit
Result: Mild skin irritation - 24 h
Serious eye damage/eye irritation Eyes - Rabbit
Result: Mild eye irritation - 24 h
(OECD Test Guideline 405)
Respiratory or skin sensitisation No data available
Germ cell mutagenicity Hamster Lungs Micronucleus test
Hamster ovary
Sister chromatid exchange
Rat
DNA damage
Carcinogenicity
This product is or contains a component that is not classifiable as to its carcinogenicity
based on its IARC, ACGIH, NTP, or EPA classification. Limited evidence of carcinogenicity in animal studies
IARC: No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.